Product ID:REFRIGERANT 12
MSDS Date:08/21/1989
FSC:6850
NIIN:00-405-9385
MSDS Number: BLRQN

VALVOLINE OIL CO

200 E MAIN ST
LEXINGTON, KY 40512
US

Emergency Phone: 606-265-7000

Info Phone: 606-265-7000

Cage: 72527

VALVOLINE OIL CO

14000 LEXINGTON, KY 40512 US

Telephone: 606-357-7206 / 800-274-5263

Cage: 72527

DICHLORODIFLUOROMETHANE (SARA III)

CAS: 75-71-8

RTECS: PA8200000

Fraction By Weight: 100%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: CAN CAUSE SEVERE IRRITATION.
SKIN: CONTACT WITH LIQUID CAN RESULT IN FREEZING OF TISSUE.
INHALATION: EXCESSIVE INHALATION OF VAPORS CAN CAUSE NASAL AND
RESPIRATORY IRRITATION, CNS EFFECTS. IN GESTION: CAN CAUSE
GASTROINTESTINAL IRRITATION.
Effects of Overexposure:EYES: REDNESS, TEARING, BLURRED VISION. SKIN:
FREEZING OF TISSUE. INHALATION: DIZZINESS, WEAKNESS, FATIGUE,
NAUSEA, HEADACHE AND POSSIBLE UNCONSCIOUSNESS, AND EVEN DEATH.
INGESTION: NAUSEA, VOMITIN G, AND DIARRGEA.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:SKIN: SLOWLY WARM THE AFFECTED AREA WITH TEPID WATER. GET
MEDICAL ATTENTION. EYES: FLUSH WITH LARGE AMOUNTS OF WATER,
LIFTING UPPER AND LOWER LIDS OCCASIONALLY, GET MEDICAL ATTENTION.
INGESTION: DO NOT INDUCE VOMITING, KEEP PERSON WARM AND QUIET, AND
GET MEDICAL ATTENTION. INHALATION: REMOVE INDIVIDUAL TO FRESH AIR.
ADMINISTER BREATHING SUPPORT MEASURES IF NECESSARY.

Extinguishing Media:AS APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WITH A
FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE..
Unusual Fire/Explosion Hazard:NONE

Spill Release Procedures:SMALL SPILL: VENTILATE AREA AND ALLOW TO
EVAPORATE. LARGE SPILL: ALLOW TO EVAPORATE. PERSONS NOT WEARING
PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA UNTIL LEAK HAS
BEEN REPAIRED.
Neutralizing Agent:NONE

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE

Respiratory Protection:NIOSH/MSHA RESPIRATORS (NEGATIVE PRESSURE TYPE)
WHEN NEEDED.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:RESISTANT GLOVES SUCH AS POLYVINYL ALC
Eye Protection:CHEMICAL SPLASH GOGGLES
Other Protective Equipment:NORMAL WORK CLOTHING COVERING ARMS AND LEGS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE

HCC:G3
Boiling Pt:B.P. Text:-22F,-30C
Vapor Pres:4700 MM HG
Vapor Density:4.3
Spec Gravity:1.310
Evaporation Rate & Reference:> ETHER
Appearance and Odor:CLEAR AND COLORLESS GAS.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI METALS, POWDERED METALS, ALKALINE METALS.
Stability Condition to Avoid:HIGH TEMPERATURES AND OPEN FLAMES.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE, HYDROGEN
FLUORIDE, ETC.

Waste Disposal Methods:SMALL SPILL: ALLOW MATERIAL TO EVAPORATE. LARGE
SPILL: RETURN TO SUPPLIER FOR RECLAMATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.